盐热改性沸石粉砂浆的湿度调控效能与强度协同优化

Salt-thermally modified zeolite powder mortar: synergistic optimization of humidity regulation and mechanical strength

  • 摘要: 本研究结合无机盐改性与热处理优化沸石粉孔道结构以提升其调湿性能。试验采用25%NaCl盐溶液结合200℃热处理1 h的处理方法,显著提升了天然沸石粉的吸湿和放湿性能,最大吸湿量和放湿量分别提高了6.4倍和7.4倍。研究还探讨了不同掺量(0%-50%)沸石粉对砂浆调湿性能的影响,发现随着沸石粉掺量的增加,砂浆的吸放湿性能增强,但抗压和抗折强度受到影响。试验结果表明,在沸石含量为50%时,吸湿能力提高了19.5%,放湿能力增强了46.8%。改性沸石粉砂浆在提高调湿性能的同时,也影响了砂浆的力学性能,尤其是在抗压强度方面,在沸石含量为10%时抗压强度达到峰值22.9 MPa,而抗折强度则随着沸石含量增加逐步下降,在沸石含量为50%时抗折强度降低了49.0%。本研究尝试为沸石粉在调湿材料领域的应用提供一定的技术思路,并为建筑围护结构湿度调控探索性地提出一种低成本、可持续的解决方案。未来研究可进一步聚焦不同改性条件对沸石粉性能的影响规律,及其在实际复杂环境中的适用性潜力。

     

    Abstract: This study integrated inorganic salt modification and thermal treatment to optimize the pore structure of zeolite powder for enhancing its humidity regulation performance. The treatment method using 25% NaCl solution combined with heat treatment at 200℃ for 1 hour significantly enhanced the moisture adsorption and desorption capacities of natural zeolite powder, with the maximum moisture adsorption and desorption capacities increased by 6.4-fold and 7.4-fold, respectively. Additionally, the study investigated the effects of different dosages (0%-50%) of zeolite powder on the humidity regulation performance of mortar, and found that the moisture adsorption and desorption performance of the mortar increased with the increase of zeolite powder dosage, while the compressive and flexural strengths were affected. The test results showed that when the zeolite content was 50%, the moisture adsorption capacity increased by 19.5%, and the moisture desorption capacity increased by 46.8%. While modified zeolite powder mortar improved the humidity regulation performance, it also affected the mechanical properties of the mortar, especially in terms of compressive strength, which reached a peak of 22.9 MPa when the zeolite content was 10%, whereas the flexural strength gradually decreased with the increase of zeolite content, decreasing by 49.0% when the zeolite content was 50%. This study attempts to provide some technical ideas for the application of zeolite powder in the field of humidity regulation materials, and exploratorily proposes a low-cost and sustainable solution for humidity control in building envelopes. Future research can further focus on the influence rules of different modification conditions on the performance of zeolite powder and its application potential in practical complex environments.

     

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