SiC晶须增强含碳耐火材料研究进展

Research Progress on SiC Whisker-Reinforced Carbon-Containing Refractories

  • 摘要: 含碳耐火材料被广泛应用作钢水控流元件和钢包内衬材料,然而高温条件下含碳耐火材料中石墨易被氧化,特别是石墨脱溶易导致钢水增碳、影响钢水品质,含碳耐火材料的低碳化成为发展趋势。但低碳化使耐火材料弹性模量、热导率及与钢渣不润湿性下降,劣化其抗渣性、抗热震性等关键性能。通过引入陶瓷增强相优化含碳耐火材料显微结构是提升其性能重要方法。SiC晶须因高强度、高弹性模量、高热稳定性等特性常被用做含碳耐火材料增强相,较多研究通过原位生成或预合成后直接添加将其引入以提升含碳耐火材料力学性能、抗热震性、抗渣侵蚀性和抗氧化性。本文对SiC晶须增强含碳耐火材料性能的相关研究进行综述,从SiC晶须的引入方式及晶须在含碳耐火材料中的分布两方面,总结分析SiC晶须对含碳耐火材料性能的增强效果及作用机制,并对未来的研究方向进行了展望。

     

    Abstract: Carbon-containing refractories are widely used in molten steel flow control functional refractories and ladle lining materials. However, under high-temperature service conditions, graphite in carbon-containing refractories is prone to oxidation. In particular, graphite dissolution easily leads to carbon pickup in molten steel, which affects the quality of molten steel. Therefore, low-carbonization of carbon-containing refractories has become a development trend. Nevertheless, low-carbonization reduces the elastic modulus, thermal conductivity, and non-wettability with steel slag of refractories, deteriorating their key properties such as slag resistance and thermal shock resistance. At present, introducing ceramic reinforcing phases to optimize the microstructure and improve the performance of carbon-containing refractories has become an important research direction.Silicon carbide (SiC) whiskers are often used as reinforcing phases in carbon-containing refractories due to their characteristics of high strength, high elastic modulus, and high thermal stability.Numerous studies have introduced SiC whiskers either through in-situ generation or direct addition after pre-synthesis to enhance the mechanical properties, thermal shock resistance, slag erosion resistance, and oxidation resistance of carbon-containing refractories. This paper reviews the research on the performance enhancement of carbon-containing refractories by SiC whiskers. From the aspects of the introduction methods of SiC whiskers and their distribution in carbon-containing refractories, it summarizes and analyzes the enhancement effects and mechanisms of SiC whiskers on the properties of carbon-containing refractories, and prospects the future research directions.

     

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