石蜡/碱改性污泥生物炭定形相变材料的制备及性能

Preparation and properties of paraffin/alkali modified sludge biochar shape-stabilized phase change material

  • 摘要: 针对石蜡相变材料在熔融状态下易发生泄漏的问题以及市政污泥资源化处置的双重需求,以市政污泥为原料制备碱改性污泥生物炭作为支撑材料,引入槐糖脂表面活性剂提升石蜡与生物炭基体的相容性,通过真空浸渍法制备了石蜡/碱改性污泥生物炭定形相变材料。研究表明,经NaOH改性后,污泥生物炭的比表面积由46.38 m2/g增大至90.61 m2/g,总孔容增加了42.3%,对石蜡的吸附固定能力明显增强。引入质量分数为10%的槐糖脂后,定形相变材料的石蜡泄漏率降低至3.35%,相变潜热提高到36.7 J/g,增幅为42.2%,显示出良好的封装稳定性和蓄热效率。热重分析显示该材料在100℃以下未发生明显的质量损失,且热循环200次后形状和相变潜热依然保持稳定,证明所制备材料具备优异的热循环稳定性和可靠性;蓄放热性能测试进一步证实其具有有效的控制温度波动和热缓冲能力。基于污泥生物炭制备的定形相变材料能够为市政污泥的资源化利用提供新的技术路径,并为高性能、低成本固-液复合相变储能材料的研发开辟新思路。

     

    Abstract: In response to the issue of paraffin phase change materials being prone to leakage in the molten state, as well as the dual demands of municipal sludge treatment and resource utilization, an alkali-modified biochar derived from municipal sludge was developed as a supporting matrix. Sophorolipid was introduced as a surfactant to improve the interfacial compatibility between paraffin and the biochar substrate. Paraffin/alkali modified biochar shape-stabilized phase change materials were successfully fabricated via vacuum impregnation. Experimental results indicated that NaOH modification significantly enhanced the porous structure of the biochar, with the specific surface area increasing from 46.38 m2/g to 90.61 m2/g, and the total pore volume increasing by 42.3%, thereby substantially improving the paraffin adsorption capacity. Upon the addition of 10 wt% sophorolipid, the leakage rate of the shape-stabilized phase change material was reduced to 3.35%, while the latent heat increased from 25.8 J/g to 36.7 J/g, representing an enhancement of 42.2%, which demonstrates excellent encapsulation stability and thermal energy storage performance. Thermogravimetric analysis revealed that the material exhibited negligible mass loss below 100 ℃. Moreover, after 200 thermal cycling tests, the shape integrity and latent heat remained stable, confirming the material's excellent thermal cycling stability and operational reliability. The thermal energy storage and release performance tests further indicated that the material possesses effective temperature fluctuation control and thermal buffering capabilities. The development of shape-stabilized phase change materials based on sludge-derived biochar not only provides a novel technical route for the resource recovery of municipal sludge but also offers a promising strategy for the design and fabrication of high-performance, low-cost solid-liquid composite phase change materials for thermal energy storage applications.

     

/

返回文章
返回