超疏水-阻燃协同涂层的构建、机制与应用进展

Advances in the Construction, Mechanisms, and Applications of Superhydrophobic-Flame Retardant Synergistic Coatings

  • 摘要: 超疏水-阻燃协同涂层作为一种集成特殊润湿性能与火灾防护功能的多功能材料,有效克服了单一超疏水涂层仅疏水防污及传统阻燃涂层耐水性差的固有缺陷,在高危环境防护领域展现出巨大应用潜力。本文系统阐述了超疏水理论基础,分析了构建微/纳米级分层粗糙结构与引入低表面能物质的作用机制。比较了喷涂法、溶胶-凝胶法、接枝共聚法等制备方法的优缺点。重点介绍了阻燃机制与超疏水协同增效,包括气相阻燃和凝聚相阻燃。归纳了极限氧指数(LOI)、UL-94等测试分析的关键参数;详细分析了氮/磷基阻燃及其硅协同体系、金属化合物基阻燃体系和碳基微纳米阻燃材料等的作用特点及协同效应。此外,分析了改性后对复合材料防水性、热稳定及阻燃性、耐磨损以及防腐性能的影响规律,发现具有刚性骨架和含氟硅烷的涂层耐碱性更优。最后,阐述了超疏水-阻燃研究中存在的一些问题并对未来的研究方向进行了展望,建议从优化制备工艺开发、环保材料、增强阻燃层和疏水层界面结合、提高抗碱性能等方面进行研究。

     

    Abstract: As a multifunctional material integrating special wetting properties and fire protection functions, the superhydrophobic-flame retardant synergistic coating effectively overcomes the inherent defects of single superhydrophobic coatings (Only hydrophobic anti-fouling) and traditional flame retardant coatings (poor water resistance), showing great application potential in the field of high-risk environment protection. This paper systematically elaborates on the theoretical basis of superhydrophobicity and analyzes the mechanism of constructing micro/nano hierarchical rough structures and introducing low surface energy substances. It compares the advantages and disadvantages of preparation methods such as spraying, sol-gel, and graft copolymerization. The focus is placed on the synergistic effect between flame retardant mechanisms and superhydrophobicity, including gas-phase flame retardancy and condensed-phase flame retardancy. It summarizes the key parameters of testing and analysis methods such as Limiting Oxygen Index (LOI) and UL-94 test, and analyzes in detail the characteristics and synergistic effects of nitrogen/phosphorus-based flame retardant and its silicon synergistic systems, metal compound-based flame retardant systems, and carbon-based micro-nano flame retardant materials. Furthermore, it explores the influence laws of modification on the water resistance, thermal stability and flame retardancy, wear resistance, and corrosion resistance of composite materials, and finds that coatings with a rigid skeleton and fluorinated silane exhibit superior alkali resistance. Finally, it expounds on some existing problems in the research of superhydrophobic-flame retardancy and prospects for future research directions, suggesting efforts in optimizing preparation processes, developing environmentally friendly materials, enhancing the interface bonding between flame retardant layers and hydrophobic layers, and improving alkali resistance.

     

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