二氧化硅气凝胶封装对钙钛矿量子点发光性能的影响

Effect of silica aerogel encapsulation on the photoluminescence properties of perovskite quantum dots

  • 摘要: 具有高荧光效率和高色纯度的钙钛矿量子点(PQDs)在显示领域具有广阔的应用前景,但环境稳定性差一直是限制其商业化的关键因素。介孔材料封装被认为是提升钙钛矿量子点稳定性的有效方式,本文以疏水性基团改性后的二氧化硅气凝胶作为封装基体,成功合成了二氧化硅气凝胶(SiO2 AGs)封装钙钛矿量子点复合材料(简称MAPbX3@AGs),并获得了450-598 nm的可调发光,研究了二氧化硅气凝胶封装对钙钛矿量子点发光性能的影响。结果表明MAPbX3 PQDs沉积在二氧化硅气凝胶的纳米孔隙中,二氧化硅气凝胶为钙钛矿量子点提供了良好的屏障,有效抑制了光照、热和水分引起的降解,同时二氧化硅气凝胶表面的疏水性基团进一步削弱了水分对钙钛矿量子点的侵蚀作用。MAPbBr3@AGs复合材料表现出优异的环境稳定性,尤其是在水中浸泡6天仍保持初始荧光强度的69.7%。

     

    Abstract: Perovskite quantum dots (PQDs), known for their high fluorescence efficiency and excellent color purity, hold great promise for display applications. However, their poor environmental stability remains a major obstacle to commercialization. Encapsulation using mesoporous materials has emerged as an effective strategy to enhance the stability of PQDs. In this study, silica aerogel (SiO2 AGs) was employed as the encapsulation matrix to successfully synthesize silica aerogel-encapsulated perovskite quantum dot composites (denoted as MAPbX3@AGs), which exhibited tunable photoluminescence in the range of 450–598 nm. The effects of silica aerogel encapsulation on the optical properties of PQDs were systematically investigated. The results show that MAPbX3 PQDs are embedded within the nanopores of the silica aerogel, which serves as an effective physical barrier against degradation caused by light, heat, and moisture. In addition, the hydrophobic groups on the surface of the aerogel further reduce moisture penetration, offering additional protection to the PQDs. Notably, the MAPbBr3@AGs composite demonstrated excellent environmental stability, retaining 69.7% of its initial photoluminescence intensity even after immersion in water for six days.

     

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