全固态高压锂离子电池正极/电解质界面稳定性提升策略研究进展

Research progress on strategies to improve the interface stability of cathode/electrolyte in all-solid-state high-voltage lithium-ion batteries

  • 摘要: 高压下的界面稳定性是阻碍高性能全固态电池发展的棘手问题。优化正极/电解质界面(CEI)稳定性是目前的主流方法,均匀稳定的CEI能够显著提高电池的循环性能。但是CEI的成分较为复杂,厚度以及均匀性较难控制,且其离子电导率和稳定性较差等问题严重阻碍了锂离子电池的发展。本文首先阐述了CEI的组成和结构,随后,介绍了CEI的形成机理以及作用,在此基础上,系统分析了提高CEI性能的改性策略,包括锂盐优化、添加剂优化、人工构筑CEI等方法对CEI进行改善。最后,指出CEI在研究过程中面临的挑战和未来的发展趋势。

     

    Abstract: At present, poor interfacial stability at high voltage is a thorny problem hindering the development of high-performance all-solid-state batteries. Optimizing the cathode/electrolyte interphase (CEI) is currently the mainstream method, and a uniform and stable CEI can significantly improve the cycling performance of the battery. However, the composition of CEI is complex, the thickness and uniformity are difficult to control, and its ionic conductivity and stability are poor, which seriously hinder the development of lithium-ion batteries.Therefore, it is extremely important to optimize the performance and stability of CEI. In this paper, the composition and structure of CEI are first expounded, and then the formation mechanism and function of CEI are introduced, and then the modification strategies to improve the performance of CEI are systematically analyzed, such as the improvement of CEI by lithium salt optimization, additive regulation, artificial construction of CEI, etc., and finally, the challenges and future development trends of CEI in the research process are summarized.

     

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