连续碳纤维增强聚芳醚酮热塑性复合材料在航空领域的研究及应用进展

Research and application progress of continuous carbon fiber reinforced polyaryletherketone thermoplastic composites in the aviation field

  • 摘要: 高性能热塑性复合材料具有比传统热固性复合材料更好的抗冲击性能,兼具优异的可焊接性,有望减少紧固件使用,从而可以实现飞行器更好的减重效果,因此,高性能热塑性复合材料未来在航空领域具有重要的潜在应用价值。其中,聚芳醚酮(PAEK)类复合材料不仅具有良好的冲击韧性,而且耐高温、耐溶剂、抗疲劳,是综合性能表现较为突出的高性能热塑性复合材料。早期的研究,主要集中于聚醚醚酮(PEEK)复合材料和聚醚酮酮(PEKK)复合材料。然而,聚醚醚酮树脂的熔融温度较高为343℃,其成型温度高达390℃,一直以来聚醚醚酮复合材料较高的成型温度和成型压力限制了其在航空领域的推广应用。近年来,随着具有低熔融温度的聚芳醚酮(LMPAEK)树脂(Tm<320℃)开发成功,聚芳醚酮复合材料的成型工艺性得到显著改善,特别是在自动铺放成型技术方面,有望实现真正意义上的自动铺放原位成型。聚芳醚酮复合材料自动铺放成型及焊接技术的发展,对于降低复合材料制造成本、提高产品质量一致性和实现飞行器减重具有重要作用,对于推动聚芳醚酮复合材料在航空领域的应用具有重要意义。本文综述了近年来聚芳醚酮树脂及复合材料、自动铺放技术、焊接技术及其在航空领域的研究及应用进展。

     

    Abstract: High-performance thermoplastic composites exhibit superior impact resistance compared to traditional thermosetting composites, along with excellent weldability, which is expected to reduce the use of fasteners and thereby achieve better weight reduction for aircraft. Consequently, high-performance thermoplastic composites hold significant potential for future applications in the aviation sector. Among these, polyaryletherketone (PAEK) composites not only exhibit excellent impact toughness but also demonstrate high-temperature resistance, solvent resistance, and fatigue resistance, making them a class of high-performance thermoplastic composites with outstanding comprehensive properties. Early research primarily focused on polyetheretherketone (PEEK) composites and polyetherketoneketone (PEKK) composites. However, PEEK resin has a high melting temperature of 343℃, with a forming temperature reaching up to 390℃. The high forming temperature and pressure of PEEK composites have long hindered their widespread adoption in the aviation industry. In recent years, with the successful development of low-melting-temperature polyaryletherketone (LMPAEK) resins (Tm < 320℃), the processability of PAEK composites has significantly improved, particularly in automated fiber placement (AFP) technology, making it possible to achieve true in-situ consolidation during automated layup. The advancement of automated fiber placement and welding technologies for PAEK composites plays a crucial role in reducing manufacturing costs, improving product consistency, and enabling aircraft weight reduction. These developments are of great significance in promoting the application of PAEK composites in the aviation field. This paper provides a comprehensive review of recent research and application advancements in PAEK composites, AFP technology, welding techniques, and their utilization in the field of aviation.

     

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