ZrO2 层状复合陶瓷的显微结构及晶体学位向关系

MICROSTRUCTURE AND CRYSTAL ORIENTATION RELATIONSHIPOF ZrO2 LAMINATED CERAMICS

  • 摘要: 利用扫描和透射电子显微镜及X-rays 衍射仪等, 对ZrO2 层状复合陶瓷的显微形貌特征、断裂相变量及晶体学位向关系进行了深入研究。研究结果表明, ZrO2 层状陶瓷由于界面压应力的作用, 抑制了烧结过程中晶粒的生长速度及冷却后四方相向单斜相的转变, 提高了可相变四方相的含量, 提高了断裂相变量, 改善了材料的力学性能, 但却没有改变四方相和单斜相之间的晶体学位向关系, 在层状ZrO2 陶瓷中, (100) m/ / (010) t 的晶体学位向关系仍然存在。

     

    Abstract: The micro-appearance feature , the formation of twin lines of monoclinic , the phase transformation and thecrystal orientation relationship of ZrO2 laminated ceramics were studied by scanning electron micro scope (SEM) ,transmission electron microscope ( TEM) , X-rays instruments , etc1The experiment results show that the interface compressivestresses can decrease the rate of the grains growth , control the transformation of tetragonal during sintering , raise theamount of the transformable tetragonal , strengthen the effect of the transformation effect , but do not change the orientation relation between tetragonal and monoclinic phase , while (100) m/ / (010) t still exist1

     

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