碳纳米管对丁腈橡胶O型密封圈力学及其热稳定性能的影响

Effect of carbon nanotubes on mechanical and thermal stability of nitrile rubber O-ring

  • 摘要: 为了研究碳纳米管(CNT)对丁腈橡胶(NBR) O型密封圈的力学及热稳定性能补强机制,利用机械共混法和热压成型法制备了1%CNT/NBR (CNT质量比)和2%CNT/NBR复合材料的O型密封圈,在表征CNT/NBR复合材料的截面SEM、EDS和FTIR基础上,测试了CNT/NBR复合材料O型密封圈的力学性能、热稳定性能和老化性能。研究结果表明,随着CNT含量的增加,CNT/NBR复合材质O型密封圈的弹性模量增大,刚性增强。1%CNT/NBR材质O型密封圈由于C—O键的形成,使其拉伸强度达到12.6 MPa。CNT在NBR基体中含量的增加可以提高CNT/NBR复合材质O型密封圈的热稳定性,2%CNT/NBR的相转变温度达到297℃。1%CNT/NBR复合材料具有优异的抗老化特性归因于CNT使NBR基体产生C≡N三键官能团。高性能CNT/NBR复合材料O型密封圈在航空密封件领域有一定的应用价值。

     

    Abstract: In order to study the reinforcing mechanism of carbon nanotubes (CNT) on the mechanical and thermal stability of nitrile rubber (NBR) O-ring, 1%CNT/NBR (mass ratio of CNT) and 2%CNT/NBR composite O-ring were prepared by mechanical blending and hot pressing. The mechanical properties of CNT/NBR composite O-ring were tested on the basis of SEM, EDS and FTIR. The results show that with the increase of CNT content, the elastic modulus and rigidity of CNT/NBR composite O-ring increase. The tensile strength of 1%CNT/NBR O-ring reaches 12.6 MPa due to the formation of C—O bond. The increase of CNT content in NBR matrix can improve the thermal stability of CNT/NBR composite O-ring, and the phase transition temperature of 2%CNT/NBR reaches 297℃. The excellent aging resistance of 1%CNT/NBR composites is attributed to the fact that CNT makes NBR matrix produce C≡N triple bond functional groups. High-performance CNT/NBR composite O-ring has certain application value in the field of aviation seals.

     

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