倒置结构全无机钙钛矿太阳能电池的界面层研究进展

Recent progress of interfacial layers for inverted inorganic perovskite solar cells

  • 摘要: 铯基无机钙钛矿(CsPbX3)因其耐热性好、低成本和带隙可调等优点,近年来备受关注,并广泛用于制备新型薄膜太阳能电池。目前,虽然具有倒置结构的无机钙钛矿太阳能电池(PSC)更稳定且有望应用于构筑叠层电池的顶电池,其性能仍落后于正置结构的电池。因此,倒置电池的结构,特别是其界面层亟待进一步优化。近年来,研究者们设计和开发了一系列有机、无机界面层(包括空穴传输层和电子传输层),尝试优化基于无机钙钛矿的倒置电池。本综述针对这一现状,从材料和制备工艺的角度出发,综述了基于有机、无机材料体系的多种界面层的制备和应用进展,总结各类界面层材料的特点,讨论目前界面层的瓶颈问题和潜在的解决方案。

     

    Abstract: In recent years, cesium based inorganic perovskites (CsPbX3) are of great interest due to their high thermal resistance, low cost and tunable bandgap, which have been used as absorbers to for the development of novel thin-film solar cells. Currently, the photovoltaic performance of inverted perovskite solar cells (PSC) still leg behind that of regular solar cells, though the inverted solar cells are more stable and more promising as top layer of tandem solar cells. Therefore, the device structure of inverted solar cell remains to be further optimized. To approach this aim, researchers have developed a series of organic and inorganic interfacial layers, including hole-transport-layer and electron-transport-layer, with the aim of optimizing the inverted inorganic perovskite solar cells. Herein, we address the recent progress of organic and inorganic interfacial layers from the perspective of materials and processing techniques. A variety of material systems are compared to summarize their features. This work also discuss their bottlenecks and try to provide potential solutions for achieving ideal interfacial layers.

     

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