菠萝蜜种子淀粉可生物降解复合膜的制备及性能

Preparation and properties of jackfruit seeds starch biodegradable composite film

  • 摘要: 针对传统塑料制品难降解、污染环境等问题,选用环境友好、可降解菠萝蜜种子淀粉(JFss)、羧甲基纤维素钠(CMC)和海藻酸钠(SA)为原料,采用涂膜工艺制备了一种可生物降解复合膜。研究JFss的用量对复合膜力学性能、耐水性、水溶性、透湿性的影响及复合膜润湿性随着时间变化规律,并对复合膜进行土埋降解性测试。采用SEM、FITR、XRD和TGA对复合膜形貌、结构和热稳定性表征。结果表明,JFss的添加使复合膜拉伸强度提高35.8%,耐水性提高4.16%,水溶性提高7.8%,水蒸汽阻隔性提高153.7%,且具有良好的润湿性、保湿性和生物降解性。另外,复合膜中CMC、SA、JFss各组分形成分子间氢键,具有良好的相容性和热稳定性。本方法复合膜制备的原料廉价、制备简单,可大规模生产,在生物降解材料领域具有潜在的应用价值。

     

    Abstract: Aiming at the problems of traditional plastic products which are difficult to degrade and pollute the environment, this work selects environmentally friendly and degradable Jackfruit seeds starch (JFss), carboxymethyl cellulose (CMC) and sodium alginate (SA) as raw materials and prepares a biodegradable composite film by a coating process. The effects of the amount of JFss on the mechanical properties, water resistance, water solubility and moisture permeability of the composite membrane were investigated, as well as the changes of the wettability of the composite membrane with time, and the composite membrane was tested for soil burial degradability. SEM, FITR, XRD and TGA were used to characterize the morphology, structure and thermal stability of the composite films. The results show that the addition of JFss increases the tensile strength of the composite film by 35.8%, water resistance by 4.16%, water solubility by 7.8%, water vapor barrier by 153.7%, and has good wettability, moisture retention and biodegradability. In addition, each component of CMC, SA and JFss in the composite film forms intermolecular hydrogen bonds, which have good compatibility and thermal stability. The raw materials for the preparation of composite film by this method are inexpensive, simple to prepare, and can be produced on a large scale, which have potential applications in the field of biodegradable materials.

     

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