碳纳米管包裹聚磷酸铵协同Mg(OH)2构筑乙烯-醋酸乙烯酯共聚物复合材料及其火安全性能

Construction of hierarchical structure of carbon nanotube-encapsulated ammonium polyphosphate/Mg(OH)2 and the synergistic effect on the fire safety of ethylene-vinyl acetate copolymer

  • 摘要: 本文采用微胶囊法制备了具有多层次结构的碳纳米管包裹聚磷酸铵(APP@CNT)阻燃剂,在此基础上与Mg(OH)2复配,采用纳米复合技术制备了火安全的电线电缆用阻燃乙烯-醋酸乙烯酯共聚物(EVA)复合材料(APP@CNT/EVA-Mg(OH)2)。采用SEM、TGA、极限氧指数(LOI)、垂直燃烧(UL-94)、微型锥形量热仪(MCC),电子万能拉伸机和高阻计对阻燃EVA复合材料的结构与性能进行系统研究。结果表明,APP@CNT/EVA-Mg(OH)2的残炭率从2.4%上升至43.9%,氧指数高达38%,垂直燃烧达到UL-94 V-0级,热释放峰值(PHRR)比纯EVA下降了57.85%,总热释放(THR)下降了57.80%,屈服强度提高了408%,复合材料体积电阻率仍高达3.9×1015 Ω·cm。以上数据表明多层次结构APP@CNT协同Mg(OH)2阻燃EVA复合材料(APP@CNT/EVA-Mg(OH)2)具有良好的火安全性能。

     

    Abstract: In this paper, a hierarchical structure of carbon nanotube-encapsulated ammonium polyphosphate (APP@CNT) flame retardant was synthesized, and Mg(OH)2 was used in conjunction with nano-composite technology to prepare fire-safe wire and cable flame-retardant ethylene-vinyl acetate copolymer (EVA) composite material (APP@CNT/EVA-Mg(OH)2). The structure and performance of flame-retardant ethylene-vinyl acetate composite materials were studied by using SEM, TGA, limiting oxygen index (LOI), vertical combustion (UL-94), microscale combustion colorimeter (MCC), universal stretching machine and high resistance meter. The results show that the residual carbon rate of EVA increases from 2.4% to 43.9%, the peak heat release decreases by 57.85% compared with pure EVA, the total heat release decreases by 57.80%, and the yield strength increases by 408%. At the same time, the volume resistivity of APP@CNT/EVA-Mg(OH)2 is still as high as 3.9×1015 Ω·cm, indicating that the EVA composite material after flame retardant treatment is still an ideal wire and cable material. In addition, the oxygen index of APP@CNT/EVA-Mg(OH)2 has reached 38%, and the vertical combustion UL-94 has also reached the V-0 level, which further illustrates the hierarchical structure of APP@CNT and magnesium hydroxide. Flame-retardant ethylene-vinyl acetate composite material has high fire safety performance.

     

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