β-环糊精-聚磷酸铵对黄麻/聚丙烯复合材料阻燃性能的影响

Effect of β-cyclodextrin and ammonium polyphosphate on flame retardancy of jute/polypropylene composites

  • 摘要: 将黄麻纤维和聚丙烯纤维(PP)通过梳理、铺网和针刺的方式形成黄麻/PP复合材料毡,采用表面撒粉工艺,将阻燃剂β-环糊精(β-CD)、β-CD与聚磷酸铵(APP)复配热压后在黄麻/PP复合材料表面形成阻燃层,采用FTIR、极限氧指数测试仪、水平燃烧测试仪、锥形量热测试仪、热重分析测试仪、SEM及万能试验机等检测黄麻/PP复合材料阻燃性能、力学性能、成炭性能及样品表面微观形貌。结果表明:β-CD与APP复配后在黄麻/PP复合材料表面热压成膜可以显著提高复合材料的阻燃性能和热稳定性。当β-CD-APP复配阻燃剂质量分数为20wt%、β-CD与APP的质量比为1∶2时,黄麻/PP复合材料水平燃烧58 s后自熄,极限氧指数(LOI)值达到26.6%,根据日本JISD 1201—77标准,属于第三难燃等级材料,此时热释放速率和有效燃烧热值最小,700℃时的残炭量增加了11.68%。力学性能测试表明,在黄麻/PP复合材料表面增加阻燃层后,弯曲强度增加而拉伸强度不受影响。

     

    Abstract: The jute and polypropylene fiber (PP) were formed into jute/PP composite by carding, netting and needling. Using surface dusting process, β-cyclodextrin (β-CD), β-CD and ammonium phosphate (APP) were combined and hot pressed to form a flame-retardant layer on the surface of jute/PP composite. The flame-retardant properties, mechanical properties, carbonization properties and surface microstructure of the jute/PP composites were tested by FTIR, limit oxygen index tester, horizontal combustion tester, cone calorimeter, thermogravimetric analysis tester, SEM and universal testing machine. The results show that the thermal compression film formation on the surface of jute/PP composite after β-CD and APP compounding can significantly improve the flame retardancy and thermal stability of the jute/PP composite. When the mass ratio of β-CD to APP is 1:2 and keeping the 20wt% total content of the flame retardants, the jute/PP composite becomes extinguished after 58 s combustion. The limiting oxygen index (LOI) value is 26.6%, which reaches the third fire resistance according to Japan's JISD 1201-77 standard. The heat release rate and effective combustion calorific show the lowest value and the carbon residual at 700℃ is increased by 11.68%. The mechanical properties test of the jute/PP composites show that the flexible strength increases while the tensile strength shows little change by adding flame-retardant layer on the surface of the jute/PP composites.

     

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