Abstract: We demonstrate the recent research progress of the series novel graphene-based ordered mesoporous metal oxide composites grounded on the special 3D structure of ordered mesoporous metal oxides and the supporter of graphene, as well as the synergistic effect of coexistence. The exploratory study for controlledly synthesis of ordered mesoporous metal oxides, effective combination with graphene and photoelectric properties of composites in our lab were introduced. We outline the preparation method, formation mechanism of graphene-based ordered mesoporous metal oxide composites and their novel applications in catalysis, electrochemistry, sensing and energy storage area. The future developments of graphene-based ordered mesoporous metal oxide composites have also been prospected.